E/Me is very popular for spiking, as the inspiration mesmer line gives you alot of options for keeping your energy high.
I use E/N for my spiker though, as our guild needs someone to run corpse control (stopping the enemy from exploiting corpses by doing so first) which helps me keep my energy fairly high.
When you start the game you can try out the varoius secondary professions before making a concrete choice, maybe give a few a try before deciding on what you want to play as. And remember you can change your secondary profession later on if you change your mind.
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